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ifos โ€ข paper_2 โ€ข atomic_molecular

[UPSC IFoS 2023] Molecular Physics (Q173, 7+8=15M)

(i) Homonuclear diatomic molecules do not give any pure rotational or vibrational spectra, whereas they do give a rotational Raman spectra. Comment. (ii) The separation between the adjacent rotational Raman lines is 4B in hydrogen molecule, whereas in oxygen molecule it is 8B. Why?

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