(i) What angles do the \vec{L} \text{(vector)} make with the z-axis when l = 2 for an electron ? (ii) Determine the values of the total angular momentum for a 3d electron.

Solve the Schrodinger equation for a potential step function given by \begin{aligned} v(x) &= 0 \text{ for } x < 0 \\ &= v_0 \text{ for } x > 0 \end{aligned} and calculate the reflection and transmission coefficients. Show that for E < v_0 there is a finite probability of finding the particle in a classically forbidden region.

On the basis of uncertainty principle calculate the size of Hydrogen atom.

A stream of particles of mass M and energy E is directed from left to a one-dimensional potential well, as shown below :

The potential is -V_0 in the region a \ge x \ge -a and zero elsewhere. Set up a time-independent Schrödinger equation and obtain an expression for the transmission ratio from region I to II. Discuss the result. Show that there is a finite reflection from such a potential well, which is a result of the wave nature of matter.

The electron spin operator \hat{s} can be expressed in matrix form in terms of the Pauli spin operator, \hat{\sigma} as \hat{\sigma} = 2\hat{s} where \sigma_x = \begin{pmatrix} 0 & 1 \\ 1 & 0 \end{pmatrix}, \quad \sigma_y = \begin{pmatrix} 0 & -i \\ +i & 0 \end{pmatrix}, \quad \sigma_z = \begin{pmatrix} 1 & 0 \\ 0 & -1 \end{pmatrix} Show that \sigma_x^2 = \sigma_y^2 = \sigma_z^2 = 1 \quad \text{and} \sigma_x \sigma_y = -\sigma_y \sigma_x = i \sigma_z \sigma_y \sigma_z = -\sigma_z \sigma_y = i \sigma_x \sigma_z \sigma_x = -\sigma_x \sigma_z = i \sigma_y

Set up the time-independent Schrödinger equation for an electron moving in a Coulomb field, V(r) = \frac{-ze^2}{4\pi\varepsilon_0 r}, in polar coordinates. Solve the radial equation to get the energy eigen values.

Set up a time-independent Schrödinger equation for a linear harmonic oscillator and obtain the energy eigen values. Explain the significance of zero point energy.

Estimate the number of states lying in an energy interval of 0.03\text{ eV} above the Fermi level in a potassium crystal of unit volume. (E_F = 2.12\text{ eV} for potassium)